The earliest man-made glass objects, mainly non-transparent glass beads, are thought to date back to around 3500 BC, with finds in Egypt and Eastern Mesopotamia. In the third millennium, in central Mesopotamia, the basic raw materials of glass were being used principally to produce glazes on pots and vases. The discovery may have been coincidental, with calciferous sand finding its way into an overheated kiln and combining with soda to form a coloured glaze on the ceramics. It was then, above all, Phoenician merchants and sailors who spread this new art along the coasts of the Mediterranean.

The oldest fragments of glass vases (evidence of the origins of the hollow glass industry), however, date back to the 16th century BC and were found in Mesopotamia. Hollow glass production was also evolving around this time in Egypt, and there is evidence of other ancient glassmaking activities emerging independently in Mycenae (Greece), China and North Tyrol.